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Journal of Chemistry Volume 2018 ,2018-12-06
Enthalpies of Combustion and Formation of Histidine Stereoisomers
Research Article
A. Neacsu 1 D. Gheorghe 1 I. Contineanu 1 A. M. Sofronia 1 F. Teodorescu 2 S. Perişanu 3
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DOI:10.1155/2018/7801381
Received 2018-09-19, accepted for publication 2018-11-18, Published 2018-11-18
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摘要

The combustion energy of histidine enantiomers (L and D) and of their racemic mixture was measured experimentally. The following values for the enthalpies of formation corresponding to the crystalline state were derived (L = −451.7, D = −448.7, DL = −451.5 kJ·mol−1), and information concerning their stability was obtained by correlating the values of the above thermochemical quantity with the structure of the molecules by using the group additivity scheme. The samples were characterized using a simultaneous thermogravimetry (TG) coupled with differential scanning calorimetry (DSC) techniques in the temperature range between ambient and beyond melting-decomposition, and the corresponding parameters were calculated. The high values of the decomposition temperatures highlight the stability of the compounds. The decomposition reactions are discussed in terms of DSC and TG data, obtained by us and other researchers.

授权许可

Copyright © 2018 A. Neacsu et al. 2018
This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

图表

DSC curves for L-, D-, and DL-histidines (10°C min−1).

TG-DTG curves for L-, D-, and DL-histidines.

通讯作者

1. D. Gheorghe.Institute of Physical Chemistry “Ilie Murgulescu” of the Romanian Academy, 202 Splaiul Independentei St., 060021 Bucharest, Romania, icf.ro.gheorghedanny2@gmail.com
2. S. Perişanu.Department of General Chemistry, Polytechnic University of Bucharest, 1 St. Polizu, Bucharest, Romania, upb.ro.stefan.perisanu@upb.ro

推荐引用方式

A. Neacsu,D. Gheorghe,I. Contineanu,A. M. Sofronia,F. Teodorescu,S. Perişanu. Enthalpies of Combustion and Formation of Histidine Stereoisomers. Journal of Chemistry ,Vol.2018(2018)

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